1′-Butyl-2-methyl-1′,2,2′,3,4,9-hexahydrospiro[benzo[f]isoindole-1,3′-indole]-2′,4,9-trione
1′-Butyl-2-methyl-1′,2,2′,3,4,9-hexahydrospiro[benzo[f]isoindole-1,3′-indole]-2′,4,9-trione
Blog Article
In the title compound, C24H22N2O3, the indoline and pyrrole-fused naphthoquinone units are both essentially planar [r.m.s.deviations = 0.
042 (3) and 0.133 (3) Å, respectively].The pyrrole ring adopts a C-envelope conformation.The dihedral angle between the mean planes Others of the two five-membered rings is 89.
94 (9)°.The O atoms deviate from the mean planes of the pyrrolidine and naphthalene rings by 0.0311 (2), 0.2570 (2) and 0.
1669 (2) Å.In the crystal, C—H.O interactions generate dimers with R22(16) and R22(18) graph-set motifs.The carbonyl O atom is involved in WALL DECOR bifurcated hydrogen bonding.
C—H.π interactions also occur.